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Superexchange

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for superexchange. The endeavor fortunately paid o , as the superexchange model has proved itself to be of fundamental importance in describing a wide range of phenomenons, from Mott insulators to superconductiv-ity. The process of superexchange is a combination of di-rect exchange and electron transfer. The models for bot Superexchange (or Kramers-Anderson superexchange) is the strong (usually) antiferromagnetic coupling between two next-to-nearest neighbour cations through a non-magnetic anion. In this way, it differs from direct exchange in which there is coupling between nearest neighbor cations not involving an intermediary anion Turning back to the physical system, superexchange relies on a single-ligand orbital linking the two copper sites. (Superexchange pathways via two \ (p\) orbitals are possible, but they give rise..

Observation of isotropic-dipolar to isotropic-Heisenberg

As the magnetic interaction occurs between transition metal atoms via ligand anion, it is called superexchange interaction. In this chapter, superexchange interaction is reconsidered, from the viewpoint of molecular orbital theory. In fact, there are two direct interactions between transition metal and ligand anion Originally superexchange acquired its name because of the relatively large distances, occupied by normally diamagnetic ions, radicals, or molecules. Small exchange coupling existed even between 3dions separated by one negative ion Examples are the superexchange between transition metal atoms bridged by an oxygen at a right angle, which arises from the Coulomb exchange on the oxygen, as well as the exchange in mixed-valence compounds (Sec. 4). The competition between kinetic and double exchange is described by the Goodenough-Kanamori rules. Finally we show that exchange is not restricted to coupling spins, but can also. Automatic and instant exchange Perfect Money, USDT, BitCoin, Ethereum, Payeer, AdvCash, Dash, LiteCoin, BitCoin Cash, Zcash, Exmo, TUSD, PAX, USDC. Discount program.

The discovery of superconductivity in a ${d}^{9\ensuremath{-}\ensuremath{\delta}}$ nickelate has inspired disparate theoretical perspectives regarding the essential physics of this class of materials. A key issue is the magnitude of the magnetic superexchange, which relates to whether cuprate-like high-temperature nickelate superconductivity could be realized What does superexchange mean? (physics) An interaction of the electrons of two molecular entities mediated by one or more molecules or ions. (noun An Approach to Understanding the Electrocatalytic Activity Enhancement by Superexchange Interaction toward OER in Alkaline Media of Ni-Fe LDH. Miguel A. Oliver-Tolentino †, Juvencio Vázquez-Samperio ‡, Arturo Manzo-Robledo §, Rosa de Guadalupe González-Huerta §, Jorge L. Flores-Moreno ∥, Daniel Ramírez-Rosales ⊥, and ; Ariel. This model is superficially similar to superexchange. However, in superexchange, a ferromagnetic or antiferromagnetic alignment occurs between two atoms with the same valence (number of electrons); while in double-exchange, the interaction occurs only when one atom has an extra electron compared to the other

Superexchange - formulasearchengin

Superexchange mechanism and quantum many body excitations

The relevant magnetic superexchange interactions J 1, J 2 and J 3 are indicated; (b) and (c) are effective spin models where the sites with holes are eliminated. Such effective spin models, also augmented by relevant interchain couplings, are being used to calculate the magnetic properties. More recently we discovered that virtual excitations across the Wigner charge gap Δ W contribute to the. PHYSICAL REVIEW B 96, 085104 (2017) Enhancement of superexchange pairing in the periodically driven Hubbard model J. R. Coulthard, 1S. R. Clark,2 ,3 S. Al-Assam, 1A. Cavalleri, ,3 and D. Jaksch 4 1Clarendon Laboratory, University of Oxford, Parks Road, Oxford OX1 3PU, United Kingdom 2Department of Physics, University of Bath, Claverton Down, Bath BA2 7AY, United Kingdo Based on first-principles calculations, we investigate a novel class of 2D materials - MX2 metal dihalides (X = Cl, Br, I). Our results show that single-layer dihalides are energetically and dynamically stable and can be potentially exfoliated from their bulk layered forms. We found that 2D FeX2, NiX2, CoCl2 Recent Open Access Article Riesen Sortiment an Kompletträdern. Felgen + Markenreifen = A.T.U

What are synonyms for superexchange? ENGLISH DICTIONARY; SYNONYMS; TRANSLATE; GRAMMAR . GRAMMAR A-Z ; SPELLING ; PUNCTUATION ; WRITING TIPS ; USAGE ; EXPLORE . WORD ORIGINS ; LANGUAGE QUESTIONS ; WORD LISTS; SPANISH DICTIONARY; More. GRAMMAR . GRAMMAR A-Z ; SPELLING ; PUNCTUATION ; WRITING TIPS ; USAGE ; EXPLORE . WORD ORIGINS ; LANGUAGE QUESTIONS ; WORD LISTS ; SPANISH DICTIONARY; Site langu Definition of superexchange in the Definitions.net dictionary. Meaning of superexchange. What does superexchange mean? Information and translations of superexchange in the most comprehensive dictionary definitions resource on the web Superexchange, or Kramers-Anderson superexchange, is the strong (usually) antiferromagnetic coupling between two next-to-nearest neighbour cations through a non-magnetic anion

Recent experiments on semiconductor quantum dots have demonstrated the ability to utilize a large quantum dot to mediate superexchange interactions and generate entanglement between distant spins. This opens up a possible mechanism for selectively coupling pairs of remote spins in a larger network of quantum dots. Taking advantage of this opportunity requires a deeper understanding of how to. The molecules serve as efficient mediators for electron superexchange between the dots, while the dots themselves play the complementary role for hole transport between molecules. The network thus exhibits a double superexchange. In addition to enhancing carrier hopping rates, double superexchange plays a central role in mediating efficient polaron dissociation. Photoluminescence, dissociation. Long-Distance Superexchange between Semiconductor Quantum-Dot Electron Spins Phys Rev Lett. 2021 Jan 8;126(1):017701. doi: 10.1103/PhysRevLett.126.017701. Authors Haifeng Qiao 1 , Yadav P Kandel 1 , Saeed Fallahi 2 3 , Geoffrey C Gardner. This site uses cookies. By continuing to use this site you agree to our use of cookies. To find out more, see our Privacy and Cookies policy

Intramolekularer Elektronentransfer ist in der Chemie eine Redoxreaktion, die über eine kovalente Verknüpfung (Brücke) zwischen oxidierenden und reduzierenden Reaktanden abläuft.Weil dafür die Bildung überbrückter Zwischenprodukte erforderlich ist, treten intramolekulare Reaktionen nur bei Komplexverbindungen mit kleinen Liganden auf Ab initio Quantum Monte Carlo Calculations of Spin Superexchange in Cuprates: The Benchmarking Case of Ca 2 CuO 3 Kateryna Foyevtsova, Jaron T. Krogel, Jeongnim Kim, P. R. C. Kent, Elbio Dagotto, and Fernando A. Reboredo Phys. Rev. X 4, 031003 - Published 8 July 201

Scanning Probe Methods Group

In some cases, the sign of the superexchange interaction is definitely determined from the symmetry relations. The cases in which each cation is subject to an octahedral cubic field and the lines connecting the interacting cations to the intervening anion make an angle of either 180° or 90° are discussed in particular. Our discussion of the 180° case is applicable to crystals of the. Hopping and superexchange are generally considered to be alternative electron-transfer mechanisms in molecular systems. In this work we used mixed-valence radical cations as model systems for the. Path of Exile is a free online-only action RPG under development by Grinding Gear Games in New Zealand

Structural, Magnetic and Transport Properties of B-Site

Superexchange Interaction SpringerLin

Quantum mechanical superexchange interactions form the basis of quantum magnetism in strongly correlated electronic media. We report on the direct measurement of superexchange interactions with ultracold atoms in optical lattices. After preparing a spin-mixture of ultracold atoms in an antiferromagnetically ordered state, we measure a coherent superexchange-mediated spin dynamics with coupling. Superexchange, or Kramers-Anderson superexchange, is the strong (usually) antiferromagnetic coupling between two next-to-nearest neighbour cations through a non-magnetic anion.wikipedia. 24 Related Articles [filter] John B. Goodenough. 100% (1/1) John Goodenough John Bannister Goodenough J. B. Goodenough. A set of semi-empirical rules were developed by John B. Goodenough and Junjiro Kanamori.

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Vibronic superexchange of Ni 3+-O-Mn 3+ in La 2 NiMnO 6 nanoparticles brings the optimal e g electron filling state of Mn and Ni ions toward unity. Moreover, a vibronic superexchange interaction of Ni 3+-O-Mn 3+ induces strong Jahn-Teller distortion of MnO 6 and NiO 6 octahedra, elongating metal-O bonds, which helps to form the active species of Mn/Ni hydroxide/oxide on the surface of. Abstract A comparison is made between different methods of describing superexchange involving paramagnetic cations in non-conducting solids and molecular complexes. A description is given of the methods of Kramers (section 2), Anderson (section 4), Jansen and co-workers (section 3), Hay, Thibeault and Hoffmann (section 5.1), Harcourt (section 5.1) and of Kahn and Briat (section 5.2)

Phys. Rev. B 101, 014431 (2020) - Modulating superexchange ..

  1. The weak superexchange coupling was found to be temperature dependent and this dependence is very specific to a crystal or molecular structure. In most cases temperature dependence of superexchange is governed by thermal crystal lattice contraction. A phenomenological model of competing potential and kinetic exchange is presented and used for description of copper(II) compounds with opposite.
  2. It is shown that the usual three-center cation-anion-cation model or fourth-order pertrubation expression (in the Cu-O hopping parameter [ital t][sub [ital p][ital d]]) does not give a useful (even qualitative) estimate for the superexchange [ital J], even though, by coincidence, it predicts a.
  3. Abstract. The magnitude of superexchange interaction of the MnO crystal is calculated according to the methods proposed previously. Various mechanisms of supe
  4. Zugehörige Institution(en) am KIT: Institut für Funktionelle Grenzflächen (IFG) Institut für Nanotechnologie (INT) Publikationstyp: Zeitschriftenaufsat
  5. Figure \(\PageIndex{3}\): The result of superexchange behavior whereby all electrons of the left-side Mn 3+ are rotated to be antiparallel to the right-side Mn 3+, so that both match the spins of the bonding orbitals of the O 2-ion. The spontaneous magnetization of ferrimagnetic materials originates from the non-zero net magnetic moments when filling up the d orbitals of transition metal ions.
  6. In this paper we investigate superexchange, as a means of indirect exchange interaction between two single electron spin qubits, each embedded in a single semiconductor quantum dot (QD), mediated by an intermediate, empty QD. Our results suggest the existence of supersweet spots, in which the qubit operations implemented by superexchange interaction are simultaneously first-order.

Superaustausch - Wikipedi

TY - CONF. T1 - Superexchange Pathway for Different Coordination Modes of Carbonato Bridge. AU - Vicente, R. AU - Escuer, A. AU - Kumar, S. B. AU - Penalba, E Literatur vom gleichen Autor. auf ERef Bayreuth. Linear-response description of superexchange-driven orbital ordering in K 2 CuF 4. Mußhoff, Julian; Zhang, Guoren; Koch, Erik; Pavarini, Eva. Woodbury, NY / The American Institute of Physics (2019) [Fachzeitschriftenartikel] Physical review / B Band: 100 Ausgabe: 4 Seite(n): 04511 Autor: Curutchet, C. et al.; Genre: Zeitschriftenartikel; Im Druck veröffentlicht: 2010; Titel: Superexchange-mediated electronic energy transfer in a model dya

Role of Superexchange Interaction on Tuning of Ni/Li

  1. Physical examples being studied in our group are superexchange antiferromagnetic coupling in cuprates, and the spin chemistry of Fe-porphyrns. In these systems, localized 3d orbitals on the metal centers induce strong correlation effects which must be treated on the same footing as electron hopping between the centers. A further system of general interest is the uniform electron gas, where our.
  2. Borohydride as Magnetic Superexchange Pathway in Late Lanthanide Borohydrides. Weinheim / Wiley-VCH (2019) [Fachzeitschriftenartikel] European journal of inorganic chemistry Band: 2019 Ausgabe: 13 Seite(n): 1776-1783. Autorinnen und Autoren. Ausgewählte Autorinnen und Autoren. Wegner, Wojciech van Leusen, Jan Majewski, Jacek Grochala, Wojciech Kögerler, Paul. Identifikationsnummern. DOI: 10.
  3. We find evidence for a superexchange mediated mechanism, whereby the fission process proceeds through virtual charge-transfer states which may be very high in energy. In particular, this mechanism predicts efficient singlet fission on the sub-picosecond timescale, in reasonable agreement with experiment. We investigate the role played by molecular vibrations in mediating relaxation and.
  4. Donate to arXiv. Please join the Simons Foundation and our generous member organizations in supporting arXiv during our giving campaign September 23-27. 100% of your contribution will fund improvements and new initiatives to benefit arXiv's global scientific community

Superexchange interaction and symmetry properties of

  1. Superexchange The theory of superexchange couplings in ionic solids is reviewed using a configuration-interaction approach. A discussion is given of the origin of the Kanamori-Goodenough (KG) rules taking into account lack of orthogonalization between atomic orbitals. It is shown that this effect can reverse the sign expected from the KG rules. Contact is made with the theory of Anderson, and.
  2. Superexchange, effective interactions, and magnetic ground states in frustrated triangular-lattice quantum magnets Applicant Dr. Liviu Hozoi Leibniz-Institut für Festkörper- und Werkstoffforschung Dresden (IFW) e.V. Institut für Theoretische Festkörperphysik. Subject Area.
  3. A generalized mechanism for superexchange BY V. HALPERN Department of Electrical Engineering, Imperial College of Science and Technology, London, S.W 7 (Communicated by D. Gabor, F.R.S.-Received 24 June 1965-Revised 4 August 1965) The concepts of bond orbitals and unrestricted Hartree-Fock orbitals are used in an attempt to explain the mechanism of superexchange between magnetic cations via an.
  4. J. Q. Lin, P. Villar Arribi, G. Fabbris, A. S. Botana, D. Meyers, H. Miao, Y. Shen, D. G. Mazzone, J. Feng, S. G. Chiuzbǎian, A. Nag, A. C. Walters, M. García.
  5. Superexchange Effects on Oxygen Reduction Activity of Edge-Sharing [Co x Mn 1 − x O 6] Octahedra in Spinel Oxide Ye Zhou, School of Materials Science & Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, 639798 Singapore. Search for more papers by this author. Shengnan Sun, School of Materials Science & Engineering, Nanyang Technological University, 50 Nanyang Avenue.
PPT - SPIN STRUCTURE FACTOR OF THE FRUSTRATED QUANTUM

Time-Resolved Observation and Control of Superexchange

Autor: Tsirlin, A. A. et al.; Genre: Zeitschriftenartikel; Im Druck veröffentlicht: 2011-10-31; Titel: Unusual ferromagnetic superexchange in CdVO3: The role of C bridge: A unified theoretical description of the superexchange and hopping mechanism E. G. Petrov, Ye. V. Shevchenko, and V. I. Teslenko Bogolyubov Institute for Theoretical Physics, Ukraine National Academy of Sciences, 14-b Metrologichna str., UA-03143 Kiev, Ukraine V. May Institu ¨tfur Physik, Humboldt-Universitat zu Berlin, Hausvogteiplatz, D-10117 Berlin, Germany ~Received 12 February. Superexchange is the underlying mechanism responsible for the creation of antiferomagnetic order in CuO and MnO [22,23], is a possible mechanism for d-wave high T c superconductivity [24], and allows for switching between ferromagnetic and anti-ferromagnetic order in cold atomic gases [25]. Although the possibility to use mediated ex- change (superexchange) was mentioned in the original Loss. The modified superexchange model shows wide possibilities to clarify the mechanism of formation of a tunneling current through terminated molecular wire. The model has no inherent rigid restrictions of the standard superexchange model. This allows to obtain the analytical expressions for the analysis of the current-voltage characteristics of the wire, in which the voltage bias does not. The superexchange mechanism proposed is made possible essentially not via spin-orbit mixing of {xy) and (x 2 y 2) — states but via configurational mixing of such functions caused by the close proximity of the second metal atom. Footnotes. This text was harvested from a scanned image of the original document using optical character recognition (OCR) software. As such, it may contain errors.

Superexchange Article about superexchange by The Free

  1. Weak antiferromagnetic superexchange interaction in fcc C60Hn Weak antiferromagnetic superexchange interaction in fcc C60Hn . A recent density-functional calculation for fcc C60Hn (n = odd) [ K.W. Lee and C. E. Lee, Phys. Rev. Lett. 106, 166402 (2011)] proposed the existence of Stoner ferromagnetism based on an itinerant band model
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  3. Here, the specifics of the bonding geometry and its implications for the superexchange interactions have to be considered seriously. On the other hand, we reported to which extent the materials made available, especially the diamagnetically diluted single crystals, prompted us to apply complex pulse ESR techniques for a better understanding of the physical properties of our compounds
  4. Linear-response description of superexchange-driven orbital ordering in K 2 CuF 4. Mußhoff, Julian; Zhang, Guoren; Koch, Erik; Pavarini, Eva. Woodbury, NY : The American Institute of Physics (2019) Journal Article. In: Physical review / B Volume: 100 Issue: 4 Page(s)/Article-Nr.: 04511

Exchange and Superexchange SpringerLin

Borohydride as Magnetic Superexchange Pathway in Late Lanthanide Borohydrides. Weinheim / Wiley-VCH (2019) [Journal Article] European journal of inorganic chemistry Volume: 2019 Issue: 13 Page(s): 1776-1783. Authors. Authors. Wegner, Wojciech van Leusen, Jan Majewski, Jacek Grochala, Wojciech Kögerler, Paul . Identifier. DOI: 10.1002/ejic.201801488; REPORT NUMBER: RWTH-2019-06324; Sources. Superexchange (or Kramers-Anderson superexchange) is the strong (usually) antiferromagnetic coupling between two next-to-nearest neighbour cations through a non-magnetic anion.In this way, it differs from direct exchange in which there is coupling between nearest neighbor cations not involving an intermediary anion superexchange. Interpretation Translation  superexchange. nadwymiana. English-Polish dictionary for engineers. 2013. superemitron; superexcitation; Look at other dictionaries: Superexchange — (or Kramers Anderson superexchange) is the strong antiferromagnetic coupling between two next to nearest neighbor positive ions through a non magnetic anion. It is caused as a result of the electrons. superexchange ['sju:pәriks'tʃeindʒ] [固物]超交換(的) English-Chinese dictionary. 2013

Phys. Rev. Lett. 126, 087001 (2021) - Strong Superexchange ..

A quantitive theory of the superexchange interaction between Ir4+ ions in ammonium hexachloroplatinate and related compounds, based on Judd's formulation, is presented. The overlap model of superexchange proposed by Bradbury and Newman is extended in order to predict magnitudes of the various parameters; the high symmetry of the pair system makes such an analysis particularly illuminating Enter. superexchange.co

Superexchange Meaning Best 1 Definitions of Superexchang

Superexchange-Driven Magnetoelectricity in Magnetic Vortices Kris T. Delaney,1 Maxim Mostovoy,2 and Nicola A. Spaldin3 1Materials Research Laboratory, University of California, Santa Barbara, California 93106-5121, USA 2Zernike Institute for Advanced Materials, University of Groningen, The Netherlands 3Materials Department, University of California, Santa Barbara, California 93106-5050, USA. Made available by U.S. Department of Energy Office of Scientific and Technical Information. Superexchange Interaction. 0 Followers. Recent papers in Superexchange Interaction. Papers; People; Characterization of Two Layered Copper(II) Coordination Polymers with Anions of 3-Phosphonopropionic Acid and (RS)-2-Phosphonobutyric Acid. Blue single crystals of Cu[μ3-O3P(CH2)2COOH].2H2O (1) and Cu[(RS)-μ3- O3PCH(C2H5)COOH].3H2O (2) have been prepared in aqueous Cu2+-solutions (pH = 2.5-3.

An Approach to Understanding the Electrocatalytic Activity

We've got 0 rhyming words for superexchange » What rhymes with superexchange? This page is about the various possible words that rhymes or sounds like superexchange.Use it for writing poetry, composing lyrics for your song or coming up with rap verses superexchange - это... Что такое superexchange? суперобме Abstract: N01.00072: Relaxation of a Single Dopant in a 2D Antiferromagnetic Insulator: Interplay of Tunneling and Superexchange* Abstract . Presenter: Lev H Kendrick (Harvard University) Authors: Lev H Kendrick (Harvard University) Geoffrey Ji (Harvard University) Muqing Xu (Harvard University) Anant Kale (Harvard University) Christie S Chiu (Princeton University) Justus Bruggenjurgen. Spin-orbital superexchange physics emerging from interacting oxygen molecules in KO 2. I V Solovyev. Published 25 January 2008 • IOP Publishing and Deutsche Physikalische Gesellschaft New Journal of Physics, Volume 10, January 200 superexchange. Interpretation Translation  superexchange. noun. An interaction of the electrons of two molecular entities mediated by one or more molecules or ions. Wikipedia foundation. photoresistance; Compton; Look at other dictionaries:.

Double-exchange mechanism - Wikipedi

Supercatalysis by superexchange. Cite Download (3.09 MB)Share Embed. journal contribution. posted on 02.12.2016, 11:44 by Stephen Fletcher, Nicholas J. Van Dijk. In modern transition state theory, the rate constant for an electron transfer reaction is expressed as the product of four factors: an exponential factor, a pre-exponential factor, an electronic transmission coefficient, and a nuclear. Man beachte bei der Aufstellung solcher Schemata eine gewisse Willkür beim Einzeichnen der Orbitale. So lassen sich die jeweils zwei O-p y - und O-p z-Orbitale so linearkombinieren, dass das abgebildete Kleeblatt an O um einen beliebigen Winkel in der Zeichenebene gedreht ist.Die Spinkopplung zu C kann daher durch ein einziges O-p-Orbital dargestellt werden, das in einer möglichst.

Goodenough-Kanamori rule - Scholarpedi

A key issue is the magnitude of the magnetic superexchange, which relates to whether cuprate-like high-temperature nickelate superconductivity could be realized. We address this question using Ni L-edge and O K-edge spectroscopy of the reduced trilayer nickelate d 9-1/3 La 4 Ni 3 O 8 and associated theoretical modeling. A magnon energy scale of ~80 meV resulting from a nearest-neighbor. Superexchange blockade in triple quantum dots. Physical Review B, 2014. Rafael Sanche superexchange published on by Oxford University Press Many translated example sentences containing superexchange - Spanish-English dictionary and search engine for Spanish translations What does SUPEREXCHANGE mean? This page is about the various possible meanings of the acronym, abbreviation, shorthand or slang term: SUPEREXCHANGE . We couldn't find any results for your search

Interpretation of the Magnetic Structures of Cu2Te2O5X2 (X: Cl, Br) and Ca3.1Cu0.9RuO6 on the Basis of Electronic Structure Considerations: Cases for Strong Super-Superexchange Interactions Involving Cu2+ Ions Superexchange interaction in cuprates. Y. Mizuno, T. Tohyama, S. Maekawa. Department of Applied Physics; Research output: Contribution to journal › Article › peer-review. 35 Citations (Scopus) Overview; Fingerprint; Abstract. Recent experiments have shown that the superexchange interaction (Formula presented) in one-dimensional (1D) cuprates is larger than that in two-dimensional (2D) ones. Superexchange interactions between the lowest crystal-field quadruplet of Np4+ ions induce a primary noncollinear order of time-odd rank 5 (triakontadipolar) moments with a secondary quadrupole order preserving the cubic symmetry of NpO2. Our study also reveals an unconventional multipolar exchange stric-tion mechanism behind the anomalous volume contraction of the NpO2 HO phase. strongly. superexchange mechanism by means of a suitable LCAO-MO ground state wave function of the single complex ion in the chain, built up taking into account the available ESR data. In a previous paper [7], hereafter referred as I, one of us (G. A.) has proposed a formalism by which it is possible to obtain quantitative information Reprint requests to authors. Please order a reprint rather than. The superexchange interaction is given approximately by: J 1 {-2V4/A2 SE}({ 1/ASE}+{ 1IUSE}) (6) The subscripts SE indicate that somewhat different values are to be used here compared for the band gap calculations, because of the different influence of multiplet structures. In the limit of small A, equation 6 will be dominated by the 1/A3 term. Especially in the case of charge transfer gap.

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